상세정보

STATISTICAL MECHANICS 
Definition of Microstate and Macrostate 
Definition of Ensemble 
The Canonical Ensemble 
Evaluation of α and β for the Canonical Ensemble 
The Grand Canonical Ensemble 
Evaluation of α, β, and γ for the Grand Canonical Ensemble 
Canonical Partition Function for a System of Noninteracting Particles 
Factorization of the Molecular Partition Function 
Density Functional Theory (DFT) 
Thermodynamics of Irreversible Processes 
Statistical Mechanics of Irreversible Processes 
Appendix: Legendre Transformations 
Appendix: The Lagrange Multipliers 
Appendix: Methods of Counting 
Appendix: Calculus of Variations 

GENERAL INTRODUCTION TO ADSORPTION IN SOLIDS 
Definitions and Terminology 
Interfacial Layer, Gibbs Dividing Surface, and Gibbs Adsorption 
Thermodynamics of Gas-Solid Adsorption 
Gases and Vapors Adsorption in Porous Materials 
Some Examples of the Application of the Volumetric Method 

MICROPOROSITY AND SURFACE AREA EVALUATION 
The Dubinin and Osmotic Adsorption Isotherms 
Langmuir and Fowler-Guggenheim Type Adsorption Isotherm Equations 
The t-Plot Method 
Additional Comments about the Application of the Dubinin and Osmotic Isotherms, the LT and the FGT Isotherm Equation Types, and the t-Plot Method in the Measurement of the Micropore Volume 
The BET Method
Horvath-Kawazoe Method 

NANOPOROUS MATERIALS MESOPOROSITY EVALUATION 
Capillary Condensation 
Macroscopic Theories to Describe Pore Condensation 
Density Functional Theory 

DIFFUSION IN POROUS MATERIALS 
Fick's Laws 
Transport, Self-Diffusion, and Corrected Coefficients 
Mean Square Displacement, the Random Walker, and Gaseous Diffusion 
Transport Mechanisms in Porous Media 
Viscous, Knudsen, and Transition Flows 
Viscous and Knudsen Flows in Model Porous Systems 
Transport in Real Porous Systems: Membranes 
Diffusion in Microporous Materials: Zeolites and Related Materials 

THE PLUG-FLOW ADSORPTION REACTOR 
Dynamic Adsorption 
The Plug-Flow Adsorption Reactor Model 
Appendix: Laplace Transforms 

AMORPHOUS POROUS ADSORBENTS: SILICA AND ACTIVE CARBON 
Basic Features of Amorphous Silica 
Amorphous Silica Morphology and Surface Chemistry 
Precipitated Amorphous Silica Synthesis 
Silica Modification 
Fundamental Characteristics of Active Carbon 
Active Carbon Morphology, Surface Chemistry, and Surface Modification 
Active Carbon Production Methods 
Some Applications of Precipitated Silica in Gas Phase Adsorption Processes 
Some Applications of Activated Carbons and Other Carbonaceous Materials in Gas-Phase Adsorption Processes 

CRYSTALLINE AND ORDERED NANOPOROUS MATERIALS 
Fundamental Characteristics of Zeolites and Mesoporous Molecular Sieves 
Structure 
Synthesis and Modification
Some Applications of Crystalline and Ordered Nanoporous Materials in Gas Separation and Adsorption Processes 

ADSORPTION FROM LIQUID SOLUTION 
Surface Excess Amount and Amount of Adsorption for Liquid-Solid Adsorption Systems 
Empirical Adsorption Isotherms Applied for the Correlation of Liquid-Solid Adsorption Equilibria in Systems Containing One Dissolved Component 
Model Description of Adsorption from the Liquid Phase on Solids 
Some Applications of Liquid-Solid Adsorption 

*All Chapters Contain an Introduction and References 

Index

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